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Size matters: if you are a bubble of volcanic gas

sc604 — Mon, 06 Aug 2018 11:13:18 +0000

A team of scientists, including a volcanologist and mathematician from the ̽��ֱ�� of Cambridge, discovered the phenomenon through detailed observations of gas emissions from Kīlauea volcano in Hawaii.

At many volcanoes around the world, gas emissions are monitored routinely to help with forecasting eruptions. Changes in the output or proportions of different gases - such as carbon dioxide and sulphur dioxide – can herald shifts in the activity of a volcano. Volcanologists have considered that these chemical changes reflect the rise and fall of magma in the Earth’s crust but the new research reveals that the composition of volcanic gases depends also on the size of the gas bubbles rising up to the surface.

Until the latest spectacular eruption opened up fissures on the flank of the volcano, Kīlauea held a vast lava lake in its summit crater. ̽��ֱ��behaviour of this lava lake alternated between phases of fiery ‘spattering’ powered by large gas bubbles bursting through the magma, and more gentle gas release, accompanied by slow and steady motion of the lava.

In the past, volcanic gases have been sampled directly from steaming vents and openings called fumaroles. But this is not possible for the emissions from a lava lake, 200 metres across, and at the bottom of a steep-sided crater. Instead, the team used an infrared spectrometer, which is employed for routine volcano monitoring by co-authors of the study, Jeff Sutton and Tamar Elias from the Hawaiian Volcano Observatory (US Geological Survey).

̽��ֱ��device was located on the edge of the crater, pointed at the lava lake, and recorded gas compositions in the atmosphere every few seconds. ̽��ֱ��emissions of carbon- and sulphur-bearing gases were measured during both the vigorous and mild phases of activity.

Each individual measurement was used to compute the temperature of the volcanic gas. What immediately struck the scientists was that the gas temperatures ranged from 1150 degrees Celsius – the temperature of the lava – down to around 900 degrees Celsius. “At this temperature, the lava would freeze,” said lead author Dr Clive Oppenheimer, from Cambridge’s Department of Geography. “At first, we couldn’t understand how the gases could emerge much colder than the molten lava sloshing in the lake.”

̽��ֱ��clue to this puzzle came from the variation in calculated gas temperatures – they were high when the lava lake was placid, and low when it was bubbling furiously. “We realised it could be because of the size of the gas bubbles,” said co-author Professor Andy Woods, Director of Cambridge’s BP Institute. “Larger bubbles rise faster through the magma and expand rapidly as the pressure reduces, just like bubbles rising in a glass of fizzy drink; the gas cools down because of the expansion.” Larger bubbles form when smaller bubbles bump into each other and merge.

Woods and Oppenheimer developed a mathematical model to account for the process, which showed a very good fit with the observations.

But there was yet another surprising finding from the gas observations from Hawaii. As well as being cooler, the emissions from the large gas bubbles were more oxidised than expected – they had higher proportions of carbon dioxide to carbon monoxide.

̽��ֱ��chemical balance of volcanic gases such as carbon dioxide and carbon monoxide (or sulphur dioxide and hydrogen sulphide) is generally thought to be controlled by the chemistry of the surrounding liquid magma but what the new findings showed is that when bubbles get large enough, most of the gas inside follows its own chemical pathway as the gas cools.

̽��ֱ��ratio of carbon dioxide to carbon monoxide when the lava lake was in its most energetic state was six times higher than during the most stable phase. ̽��ֱ��scientists suggest this effect should be taken into account when gas measurements are being used to forecast major changes in volcanic activity.

“Gas measurements are critical to our monitoring and hazard assessment; refining our understanding of how magma behaves beneath the volcano allows us to better interpret our observations,” said co-author Tamar Elias from the Hawaiian Volcano Observatory.

And there is another implication of this discovery – not for eruptions today but for the evolution of the Earth’s atmosphere billions of years ago. “Volcanic emissions in Earth’s deep past may have made the atmosphere more oxidising than we thought,” said co-author Bruno Scaillet. “A more oxygen-rich atmosphere would have facilitated the emergence and viability of life on land, by generating an ozone layer, which shields against harmful ultraviolet rays from the sun.”

Reference:
Clive Oppenheimer et al “Influence of eruptive style on volcanic gas emission chemistry and temperature” Nature Geoscience (2018). DOI: 10.1038/s41561-018-0194-5

Inset image: Clive Oppenheimer in Hawaii. Credit: Clive Oppenheimer

̽��ֱ��chemical composition of gases emitted from volcanoes – which are used to monitor changes in volcanic activity – can change depending on the size of gas bubbles rising to the surface, and relate to the way in which they erupt. ̽��ֱ��results, published in the journal Nature Geoscience, could be used to improve the forecasting of threats posed by certain volcanoes.

At first, we couldn’t understand how the gases could emerge much colder than the molten lava sloshing in the lake.

Clive Oppenheimer

Kīlauea eruption, 2018

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‘Bulges’ in volcanoes could be used to predict eruptions

sc604 — Wed, 28 Jun 2017 18:00:12 +0000

Using a technique called ‘seismic noise interferometry’ combined with geophysical measurements, the researchers measured the energy moving through a volcano. They found that there is a good correlation between the speed at which the energy travelled and the amount of bulging and shrinking observed in the rock. ̽��ֱ��technique could be used to predict more accurately when a volcano will erupt. Their results are reported in the journal Science Advances.

Data was collected by the US Geological Survey across Kīlauea in Hawaii, a very active volcano with a lake of bubbling lava just beneath its summit. During a four-year period, the researchers used sensors to measure relative changes in the velocity of seismic waves moving through the volcano over time. They then compared their results with a second set of data which measured tiny changes in the angle of the volcano over the same time period.

As Kīlauea is such an active volcano, it is constantly bulging and shrinking as pressure in the magma chamber beneath the summit increases and decreases. Kīlauea’s current eruption started in 1983, and it spews and sputters lava almost constantly. Earlier this year, a large part of the volcano fell away and it opened up a huge ‘waterfall’ of lava into the ocean below. Due to this high volume of activity, Kīlauea is also one of the most-studied volcanoes on Earth.

̽��ֱ��Cambridge researchers used seismic noise to detect what was controlling Kīlauea’s movement. Seismic noise is a persistent low-level vibration in the Earth, caused by everything from earthquakes to waves in the ocean, and can often be read on a single sensor as random noise. But by pairing sensors together, the researchers were able to observe energy passing between the two, therefore allowing them to isolate the seismic noise that was coming from the volcano.

“We were interested in how the energy travelling between the sensors changes, whether it’s getting faster or slower,” said Clare Donaldson, a PhD student in Cambridge’s Department of Earth Sciences, and the paper’s first author. “We want to know whether the seismic velocity changes reflect increasing pressure in the volcano, as volcanoes bulge out before an eruption. This is crucial for eruption forecasting.”

One to two kilometres below Kīlauea’s lava lake, there is a reservoir of magma. As the amount of magma changes in this underground reservoir, the whole summit of the volcano bulges and shrinks. At the same time, the seismic velocity changes. As the magma chamber fills up, it causes an increase in pressure, which leads to cracks closing in the surrounding rock and producing faster seismic waves – and vice versa.

“This is the first time that we’ve been able to compare seismic noise with deformation over such a long period, and the strong correlation between the two shows that this could be a new way of predicting volcanic eruptions,” said Donaldson.

Volcano seismology has traditionally measured small earthquakes at volcanoes. When magma moves underground, it often sets off tiny earthquakes, as it cracks its way through solid rock. Detecting these earthquakes is therefore very useful for eruption prediction. But sometimes magma can flow silently, through pre-existing pathways, and no earthquakes may occur. This new technique will still detect the changes caused by the magma flow.

Seismic noise occurs continuously, and is sensitive to changes that would otherwise have been missed. ̽��ֱ��researchers anticipate that this new research will allow the method to be used at the hundreds of active volcanoes around the world.

Reference
C. Donaldson et al. ‘Relative seismic velocity variations correlate with deformation at Kīlauea volcano’. Science Advances (2017) DOI: 10.1126/sciadv.1700219

Inset image: Lava Waterfall, Kilauea Volcano, Hawaii. Credit: Dhilung Kirat

A team of researchers from the ̽��ֱ�� of Cambridge have developed a new way of measuring the pressure inside volcanoes, and found that it can be a reliable indicator of future eruptions.

This could be a new way of predicting volcanic eruptions.

Clare Donaldson

Kiauea

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