
Researchers have developed a standalone device that converts sunlight, carbon dioxide and water into a carbon-neutral fuel, without requiring any additional components or electricity.
Researchers have developed a standalone device that converts sunlight, carbon dioxide and water into a carbon-neutral fuel, without requiring any additional components or electricity.
We hope this technology will pave the way toward sustainable and practical solar fuel production
Erwin Reisner
探花直播device, developed by a team from the 探花直播 of Cambridge, is a significant step toward achieving artificial photosynthesis 鈥� a process mimicking the ability of plants to convert sunlight into energy. It is based on an advanced 鈥榩hotosheet鈥� technology and converts sunlight, carbon dioxide and water into oxygen and formic acid 鈥� a storable fuel that can be either be used directly or be converted into hydrogen.
探花直播, reported in the journal Nature Energy, represent a new method for the conversion of carbon dioxide into clean fuels. 探花直播wireless device could be scaled up and used on energy 鈥榝arms鈥� similar to solar farms, producing clean fuel using sunlight and water.
Harvesting solar energy to convert carbon dioxide into fuel is a promising way to reduce carbon emissions and transition away from fossil fuels. However, it is challenging to produce these clean fuels without unwanted by-products.
鈥淚t鈥檚 been difficult to achieve artificial photosynthesis with a high degree of selectivity, so that you鈥檙e converting as much of the sunlight as possible into the fuel you want, rather than be left with a lot of waste,鈥� said first author Dr Qian Wang from Cambridge鈥檚 Department of Chemistry.
鈥淚n addition, storage of gaseous fuels and separation of by-products can be complicated 鈥� we want to get to the point where we can cleanly produce a liquid fuel that can also be easily stored and transported,鈥� said Professor Erwin Reisner, the paper鈥檚 senior author.
In 2019, researchers from Reisner鈥檚 group developed a solar reactor based on an 鈥�artificial leaf鈥� design, which also uses sunlight, carbon dioxide and water to produce a fuel, known as syngas. 探花直播new technology looks and behaves quite similarly to the artificial leaf but works in a different way and produces formic acid.
While the artificial leaf used components from solar cells, the new device doesn鈥檛 require these components and relies solely on photocatalysts embedded on a sheet to produce a so-called photocatalyst sheet. 探花直播sheets are made up of semiconductor powders, which can be prepared in large quantities easily and cost-effectively.
In addition, this new technology is more robust and produces clean fuel that is easier to store and shows potential for producing fuel products at scale. 探花直播test unit is 20 square centimetres in size, but the researchers say that it should be relatively straightforward to scale it up to several square metres. In addition, the formic acid can be accumulated in solution, and be chemically converted into different types of fuel.
鈥淲e were surprised how well it worked in terms of its selectivity 鈥� it produced almost no by-products,鈥� said Wang. 鈥淪ometimes things don鈥檛 work as well as you expected, but this was a rare case where it actually worked better.鈥�
探花直播carbon-dioxide converting cobalt-based catalyst is easy to make and relatively stable. While this technology will be easier to scale up than the artificial leaf, the efficiencies still need to be improved before any commercial deployment can be considered. 探花直播researchers are experimenting with a range of different catalysts to improve both stability and efficiency.
探花直播current results were obtained in collaboration with the team of Professor Kazunari Domen from the 探花直播 of Tokyo, a co-author of the study.
探花直播researchers are now working to further optimise the system and improve efficiency. Additionally, they are exploring other catalysts for using on the device to get different solar fuels.
鈥淲e hope this technology will pave the way toward sustainable and practical solar fuel production,鈥� said Reisner.
Reference:
Qian Wang et al. 鈥�.鈥� Nature Energy (2020). DOI: 10.1038/s41560-020-0678-6
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