Confocal microscopy image of a chiral semiconductor

Researchers have advanced a decades-old challenge in the field of organic semiconductors, opening new possibilities for the future of electronics.

It鈥檚 like working with a Lego set with every kind of shape you can imagine, rather than just rectangular bricks

Richard Friend

探花直播researchers, led by the 探花直播 of Cambridge and the Eindhoven 探花直播 of Technology, have created an organic semiconductor that forces electrons to move in a spiral pattern, which could improve the efficiency of OLED displays in television and smartphone screens, or power next-generation computing technologies such as spintronics and quantum computing.

探花直播semiconductor they developed emits circularly polarised light鈥攎eaning the light carries information about the 鈥榟andedness鈥 of electrons. 探花直播internal structure of most inorganic semiconductors, like silicon, is symmetrical, meaning electrons move through them without any preferred direction.

However, in nature, molecules often have a chiral (left- or right-handed) structure: like human hands, chiral molecules are mirror images of one another. Chirality plays an important role in biological processes like DNA formation, but it is a difficult phenomenon to harness and control in electronics.

But by using molecular design tricks inspired by nature, the researchers created a chiral semiconductor by nudging stacks of semiconducting molecules to form ordered right-handed or left-handed spiral columns. Their are reported in the journal Science.

One promising application for chiral semiconductors is in display technology. Current displays often waste a significant amount of energy due to the way screens filter light. 探花直播chiral semiconductor developed by the researchers naturally emits light in a way that could reduce these losses, making screens brighter and more energy-efficient.

鈥淲hen I started working with organic semiconductors, many people doubted their potential, but now they dominate display technology,鈥 said Professor Sir Richard Friend from Cambridge鈥檚 Cavendish Laboratory, who co-led the research. 鈥淯nlike rigid inorganic semiconductors, molecular materials offer incredible flexibility鈥攁llowing us to design entirely new structures, like chiral LEDs. It鈥檚 like working with a Lego set with every kind of shape you can imagine, rather than just rectangular bricks.鈥

探花直播semiconductor is based on a material called triazatruxene (TAT) that self-assembles into a helical stack, allowing electrons to spiral along its structure, like the thread of a screw.

鈥淲hen excited by blue or ultraviolet light, self-assembled TAT emits bright green light with strong circular polarisation鈥攁n effect that has been difficult to achieve in semiconductors until now,鈥 said co-first author Marco Preuss, from the Eindhoven 探花直播 of Technology. 鈥 探花直播structure of TAT allows electrons to move efficiently while affecting how light is emitted.鈥

By modifying OLED fabrication techniques, the researchers successfully incorporated TAT into working circularly polarised OLEDs (CP-OLEDs). These devices showed record-breaking efficiency, brightness, and polarisation levels, making them the best of their kind.

鈥淲e鈥檝e essentially reworked the standard recipe for making OLEDs like we have in our smartphones, allowing us to trap a chiral structure within a stable, non-crystallising matrix,鈥 said co-first author Rituparno Chowdhury, from Cambridge鈥檚 Cavendish Laboratory. 鈥淭his provides a practical way to create circularly polarised LEDs, something that has long eluded the field.鈥

探花直播work is part of a decades-long collaboration between Friend鈥檚 research group and the group of Professor Bert Meijer from the Eindhoven 探花直播 of Technology. 鈥淭his is a real breakthrough in making a chiral semiconductor,鈥 said Meijer. 鈥淏y carefully designing the molecular structure, we鈥檝e coupled the chirality of the structure to the motion of the electrons and that鈥檚 never been done at this level before.鈥

探花直播chiral semiconductors represent a step forward in the world of organic semiconductors, which now support an industry worth over $60 billion (about 拢45 billion). Beyond displays, this development also has implications for quantum computing and spintronics鈥攁 field of research that uses the spin, or inherent angular momentum, of electrons to store and process information, potentially leading to faster and more secure computing systems.

探花直播research was supported in part by the European Union鈥檚 Marie Curie Training Network and the European Research Council. Richard Friend is a Fellow of St John鈥檚 College, Cambridge. Rituparno Chowdhury is a member of Fitzwilliam College, Cambridge.

Reference

Rituparno Chowdhury, Marco D听Preuss et al. 鈥.鈥 Science (2025). DOI:10.1126/science.adt3011



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